|
| Section 1. Product and Company Identification |
| Product Name | Ceric Sulphate 0.1000N | Product Code | CX0612 |
|
|
|
|
| For More Information Call | In Case of Emergency Call |
| 856-423-6300 Technical Service
Monday-Friday: 8:00 AM - 5:00 PM |
800-424-9300 CHEMTREC (USA)
613-996-6666 CANUTEC (Canada) 24 Hours/Day: 7 Days/Week |
| Synonym | None. |
| Material Uses | Laboratory Reagent
|
| Chemical Family | Solution. |
| Section 2. Composition and Information on Ingredients |
| Component | CAS # | % by Weight |
| Sulfuric Acid | 7664-93-9 | 4-5 |
| Ceric Sulfate | 13590-82-4 | 3-4 |
| Water | 7732-18-5 | >91 |
| Section 3. Hazards Identification |
| Physical State and Appearance | Liquid. |
| Emergency Overview | WARNING !
MAY BE FATAL IF INHALED. CAUSES EYE AND SKIN BURNS. HARMFUL IF SWALLOWED. CAUSES RESPIRATORY TRACT IRRITATION. SUSPECT CANCER HAZARD CONTAINS MATERIAL WHICH MAY CAUSE CANCER |
| Routes of Entry | Dermal contact. Eye contact. Inhalation. Ingestion. |
| Potential Acute Health Effects |
| Eyes | Hazardous in case of eye contact (corrosive). Causes eye burns. |
| Skin | Hazardous in case of skin contact (corrosive). Skin contact produces burns. |
| Inhalation | Extremely hazardous in case of inhalation. May be fatal if inhaled. Hazardous in case of inhalation (lung irritant). |
| Ingestion | Hazardous in case of ingestion. |
| Potential Chronic Health Effects |
| Carcinogenic Effects | Classified A2 (Suspected for human.) by ACGIH [Sulfuric Acid]. |
| Additional information See Toxicological Information (section 11) |
| Medical Conditions Aggravated by Overexposure: | Repeated or prolonged contact with spray mist may produce chronic eye irritation and severe skin irritation. Repeated or prolonged exposure to spray mist may produce respiratory tract irritation leading to frequent attacks of bronchial infection. Repeated exposure to a highly toxic material may produce general deterioration of health by an accumulation in one or many human organs. |
| Section 4. First Aid Measures |
| Eye Contact | Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention immediately. |
| Skin Contact | In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Cover the irritated skin with an emollient. Cold water may be used. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention immediately. |
| Inhalation | If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately. |
| Ingestion | If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention immediately. |
| Section 5. Fire Fighting Measures |
| Flammability of the Product | Non-flammable. |
| Auto-ignition Temperature | Not applicable. |
| Flash Points | Not applicable. |
| Flammable Limits | Not applicable. |
| Products of Combustion | Not applicable. |
| Fire Hazards in Presence of Various Substances | Not applicable. |
| Explosion Hazards in Presence of Various Substances | Risks of explosion of the product in presence of static discharge: No.
Risks of explosion of the product in presence of mechanical impact: No. |
| Fire Fighting Media
and Instructions |
Not applicable. |
| Protective Clothing (Fire) | Not applicable. |
| Special Remarks on Fire Hazards | Not available. |
| Special Remarks on Explosion Hazards | Not available. |
| Section 6. Accidental Release Measures |
| Small Spill and Leak | Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container. |
| Large Spill and Leak | Stop leak if without risk. Absorb with DRY earth, sand or other non-combustible material. Do not get water inside container. Do not touch spilled material. Use water spray curtain to divert vapor drift. Use water spray to reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistance on disposal. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS and with local authorities. |
| Spill Kit Information | The following EMD Chemicals Inc. SpillSolv (TM) absorbent is recommended for this product:
SX1310 Acid Treatment Kit |
| Section 7. Handling and Storage |
| Handling | Do not ingest. Do not breathe vapor or mist. Use only with adequate ventilation. Wash thoroughly after handling. |
| Storage | Keep container tightly closed. Keep container in a cool, well-ventilated area. |
| Section 8. Exposure Controls/Personal Protection |
| Engineering Controls | Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective occupational exposure limits. Ensure that eyewash stations and safety showers are proximal to the work-station location. |
| Personal Protection |
| Eyes | Face shield. |
| Body | Full suit. |
| Respiratory | Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator when ventilation is inadequate. |
| Hands | Gloves. |
| Feet | Boots. |
|
|
| Personal Protection in Case of a Large Spill | Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self-contained breathing apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product. |
| Product Name | Exposure Limits |
| Sulfuric Acid | AUVA (Austria, 1995).
Spitzenbegrenzung: 2 mg/m3 8 times per shift, 5 minute(s). TWA: 1 mg/m3 8 hour(s). Belgium Minister of Labour (Belgium, 1998). VCD: 3 mg/m3 15 minute(s). VL: 1 mg/m3 8 hour(s). BAUA (Germany, 1997). Spitzenbegrenzung: 1 mg/m3 TWA: 1 mg/m3 8 hour(s). DK-Arbejdstylsinet (Denmark, 1996). GV: 1 mg/m3 8 hour(s). Tyterveyslaitos (Finland, 1998). STEL: 3 mg/m3 15 minute(s). TWA: 1 mg/m3 8 hour(s). INRS (France, 1996). VLE: 3 mg/m3 15 minute(s). VME: 1 mg/m3 8 hour(s). National Authority for Occupational Safety/Health (Ireland, 1999). OEL: 1 mg/m3 8 hour(s). Arbeidsinspectie (Netherlands, 1999). TGG 8 uur: 1 mg/m3 8 hour(s). N-Arbeidstylsinet (Norway, 1996). AN: 1 mg/m3 8 hour(s). AFS (Sweden, 1996). KTV: 3 mg/m3 15 minute(s). NGV: 1 mg/m3 8 hour(s). EH40-OES (United Kingdom (UK), 1997). TWA: 1 mg/m3 8 hour(s). ACGIH (United States, 1996). STEL: 3 mg/m3 15 minute(s). TWA: 1 mg/m3 8 hour(s). NIOSH REL (United States, 1994). TWA: 1 mg/m3 10 hour(s). OSHA Final Rule (United States, 1989). TWA: 1 mg/m3 8 hour(s). |
| Ceric Sulfate | Not available. |
| Water | Not available. |
| Section 9. Physical and Chemical Properties |
| Odor | Not available. |
| Color | Light yellow |
| Physical State and Appearance | Liquid. |
| Molecular Weight | Not applicable. |
| Molecular Formula | Not applicable. |
| pH | Not available. |
| Boiling/Condensation Point | The lowest known value is 99.9°C (211.8°F) (Water). Weighted average: 108.78°C (227.8°F) |
| Melting/Freezing Point | May start to solidify at -0.1°C (31.8°F) based on data for: Water. Weighted average: -0.56°C (31°F) |
| Specific Gravity | The only known value is 1.84 (Water = 1) (Sulfuric Acid). |
| Vapor Pressure | The highest known value is 0.1 kPa (1 mmHg) (@ 20°C) (Sulfuric Acid). |
| Vapor Density | Not available. |
| Odor Threshold | The lowest known value is >1 ppm (Sulfuric Acid) |
| Evaporation Rate | 0.36 (Water) compared to(n-Butyl Acetate =1) |
| LogKow | Not available. |
| Solubility | Soluble in water. |
| Section 10. Stability and Reactivity |
| Stability and Reactivity | The product is stable. |
| Conditions of Instability | Not available. |
| Incompatibility with Various Substances | Reactive with oxidizing agents, reducing agents, combustible materials, metals, acids, alkalis.
Slightly reactive to reactive with organic materials. |
| Rem/Incompatibility | Incompatible with strong reducing agents, acids,aluminum , alkalies, brass, Mg,Zn, Cu, Sn, Ni, metallic alloys and diazonium salt. |
| Hazardous Decomposition Products | SOx |
| Hazardous Polymerization | Will not occur. |
| Section 11. Toxicological Information |
| RTECS Number: |
| Cerium (IV) Sulfate | WS6960000 |
| Sulfuric Acid | WS5600000 |
| Water | ZC0110000 |
| Toxicity | Acute oral toxicity (LD50): 2140 mg/kg [Rat]. (Sulfuric Acid).
Acute toxicity of the vapor (LC50): 320 mg/m3 2 hour(s) [Mouse]. (Sulfuric Acid). |
| Chronic Effects on Humans | CARCINOGENIC EFFECTS: Classified A2 (Suspected for human.) by ACGIH [Sulfuric Acid]. |
| Acute Effects on Humans | Hazardous in case of eye contact (corrosive). Causes eye burns. Hazardous in case of skin contact (corrosive). Skin contact produces burns. Extremely hazardous in case of inhalation. May be fatal if inhaled. Hazardous in case of inhalation (lung irritant). Hazardous in case of ingestion. |
| Synergetic Products (Toxicologically) | Not available. |
| Irritancy | Draize Test: Not available. |
| Sensitization | Not available. |
| Carcinogenic Effects | Classified A2 (Suspected for human.) by ACGIH [Sulfuric Acid]. |
| Toxicity to Reproductive System | Not available. |
| Teratogenic Effects | Not available. |
| Mutagenic Effects | Not available. |
| Section 12. Ecological Information |
| Ecotoxicity | Not available. |
| BOD5 and COD | Not available. |
| Toxicity of the Products of Biodegradation | The products of degradation are less toxic than the product itself. |
| Section 13. Disposal Considerations |
| EPA Waste Number | D002 |
| Treatment | Specified technology- Neutralize to pH 6-9. Contact your local permitted waste disposal site (TSD) for permissible treatments sites.
ALWAYS CONTACT PERMITTED WASTE DISPOSER (TSD) TO ASSURE COMPLIANCE WITH ALL CURRENT LOCAL, STATE AND FEDERAL REGULATIONS. |
| Section 14. Transport Information |
| DOT Classification | Proper Shipping Name: CORROSIVE LIQUID,ACIDIC,INORGANIC,N.O.S.(CONTAINS SULFURIC ACID)
Hazard Class: 8 UN number: UN3264 Packing Group: II RQ: Not applicable. |
 |
| TDG Classification | Not available. |
| IMO/IMDG Classification | Not available. |
| ICAO/IATA Classification | Not available. |
| Section 15. Regulatory Information |
| U.S. Federal Regulations | TSCA 8(b) inventory: Ceric Sulfate; Sulfuric Acid; Water |
| SARA 302/304/311/312 extremely hazardous substances: Sulfuric Acid
SARA 302/304 emergency planning and notification: Sulfuric Acid SARA 302/304/311/312 hazardous chemicals: Sulfuric Acid SARA 311/312 MSDS distribution - chemical inventory - hazard identification: Sulfuric Acid: reactive, Immediate (Acute) Health Hazard, Delayed (Chronic) Health Hazard |
| SARA 313 toxic chemical notification and release reporting: Sulfuric Acid 4.5% |
| Clean Water Act (CWA) 307: No products were found. |
| Clean Water Act (CWA) 311: Sulfuric Acid |
| Clean air act (CAA) 112 accidental release prevention: No products were found. |
| Clean air act (CAA) 112 regulated flammable substances: No products were found. |
| Clean air act (CAA) 112 regulated toxic substances: No products were found. |
| WHMIS (Canada) | Class D-2A: Material causing other toxic effects (VERY TOXIC).
CLASS E: Corrosive liquid. |
| CEPA DSL: Ceric Sulfate; Sulfuric Acid; Water |
| This product has been classifed in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all required information. |
| International Regulations |
| EINECS | Ceric Sulfate 237-029-5
Sulfuric Acid 231-639-5 Water 231-791-2 |
| DSCL (EEC) | R38- Irritating to skin.
R41- Risk of serious damage to eyes. |
| International Lists | Australia (NICNAS): Ceric Sulfate; Sulfuric Acid; Water
Japan (MITI): Ceric Sulfate; Sulfuric Acid; Water Korea (TCCL): Ceric Sulfate; Sulfuric Acid; Water Philippines (RA6969): Ceric Sulfate; Sulfuric Acid; Water |
| China: No products were found. |
| State Regulations | Pennsylvania RTK: Sulfuric Acid: (environmental hazard, generic environmental hazard)
Massachusetts RTK: Sulfuric Acid New Jersey: Ceric Sulphate 0.1000N |
| California prop. 65: No products were found. |
| Section 16. Other Information |
|
|
|
| Changed Since Last Revision | + |
| Notice to Reader |
| The statements contained herein are based upon technical data that EMD Chemicals Inc. believes to be reliable, are offered for information purposes only and as a guide to the appropriate precautionary and emergency handling of the material by a properly trained person having the necessary technical skills. Users should consider these data only as a supplement to other information gathered by them and must make independent determinations of suitability and completeness of information from all sources to assure proper use, storage and disposal of these materials and the safety and health of employees and customers and the protection of the environment. EMD CHEMICALS INC. MAKES NO REPRESENTATION OR WARRANTY OF ANY KIND, EXPRESS OR IMPLIED, INCLUDING MERCHANTABILITY OR FITNESS FOR A PARTICULAR USE, WITH RESPECT TO THE INFORMATION HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS. |
| Ceric Sulphate 0.1000N | CX0612 | Page: 1/1 |
